The oxovanadiumiv complexes were synthesized using insitu method by refluxing the reaction mixture of 4,4,4trifluro12furyl1,3butanedione or. The oxidation of oxovanadiumiv complexes lv iv o l tetradentate schiffbase ligands such as n,n. The conventional oxidizing agents yielded mainly benzaldehyde orand benzoic acid and only a trace amount of benzil. Sometimes solvent molecules are also attached with the complexes. Download fulltext pdf oxidation of benzoin catalyzed by oxovanadiumiv schiff base complexes. Synthesis and catalytic properties of manganeseii and oxovanadiumiv complexes anchored to mesoporous mcm41. A series of new azo5pyrazolone based oxovanadiumiv complexes have been synthesized and the structures of the ligands and the complexes were fully characterized. Urease inhibition of oxovanadiumv complexes with hydrazone and hydroxamate ligands article pdf available in russian journal of coordination chemistry 409.
Pdf oxidation of benzoin catalyzed by oxovanadiumiv. Synthesis, characterization and bioactivities of some. Usually the reactions are carried out by refluxing the methanolic solution of oxovanadium salt voso4 with the ligands. Synthesis of oxovanadiumiv complexes with tetraaza. Oxovanadium iv and oxovanadium v complexes relevant to biological systems cheminform abstract. The antibacterial activities of the complexes against salmonella typhi, escherichia coli and serratia. The vanadyl xylylbicyclam complexes were highly active against hiv1 iiib and hiv2 rod strains with ic 50 values in the range 15. Studies on oxovanadium iv oxalate hydrates pdf free download. Oxovanadiumiv complexes with onno chelating ligands as catalysts for ethylene homo and copolymerization by marzena bialek, anna leksza, anna piechota, krzysztof kurzak and katarzyna koprek download pdf 866 kb. Vanadium has ability to coordinate with multidentate ligands in different geometries to produce variety of complexes.
Oxidation of benzoin catalyzed by oxovanadiumiv schiff base. Oct 20, 2000 oxovanadium iv complexes of the monosaccharides d and larabinose, dgalactose, dmannose, dlyxose, dxylose and the disaccharide maltose were obtained in aqueous solutions at ph. Although these oxovanadium iv complexes were studied intensively with tertbutylhydrogenperoxide as oxidant,, these complexes have with one exception. In an effort to study the spectral, magnetic, and stereochemical properties of vanadyl complexes, both a new series of vanadyl complexes derived from type vii ligands with subnormal magnetic moment and from type viii ligands with normal magnetic moment are synthesized and characterized. Article pdf available in chemistry central journal 71. Oxovanadiumiiiv mononuclear complexes and their linear. Oxovanadiumiv complexes of substituted n2thiophenyl. Chemical composition of 11 oxovanadiumiv vo complexes. Insitu preparation of oxovanadium iv complexes with ligands derived by condensation of furil with 1,4diaminobenzene or 3,4diaminopyridine.
Graphene oxide supported oxovanadium iv complex for. The oxidative transformation of benzoin to benzil has been accomplished by the use. Allixin is a phytoallexin found in garlic allium sativum bulbs. Pdf synthesis, molecular structure and properties of oxo. Synthesis and structural characterization of new oxovanadium. All structured data from the file and property namespaces. Oxovanadium complexes with multidentate ligands springerlink. Sarkar, synthesis, structure, magnetic properties and biological activity of supramolecular copperii. The spectral data of the complexes indicate that ligands act as tetradentate chelating agent and complexes are five coordinate. The pronounced biological activity of the metal complexes of schiff bases derived from sulfa drugs lal and. In this work, the formation of coordination compounds of oxovanadium iv with four kojic acid 5hydroxy2hydroxymethyl4pyrone derivatives was studied. Oxovanadiumiv complexes of curcumin for cellular imaging and mitochondria targeted photocytotoxicity article pdf available in dalton transactions 4335 july 2014 with 1,204. Oxovanadiumiv silsesquioxane complexes inorganic chemistry.
Electrospray ionization mass spectral fragmentation study of amino. Oxovanadiumiv complexes of halogenated oxines springerlink. Files are available under licenses specified on their description page. Pdf bactericidal activity of different oxovanadiumiv complexes. Some oxovanadiumiv complexes of porphyrin derivatives von4 type were evaluated for their. Cellular uptake and remarkable photocytotoxicity of. Synthesis and structure of oxovanadiumiv complexes vo. Synthesis, characterisation and catalytic potential of. Synthesis, reactivity, and xray crystal structure of some mixedligand oxovanadiumv complexes.
All the vanadyl complexes are crystalline, nonhygroscopic, and stable at room temperature. Oxovanadiumiv complexes 16 and the dppz bases used. The synthesised oxovanadium iv complexes were characterized by elemental analysis, electrical conductance, magnetic moment measurements and spectral infrared, electronic and electron spin resonance data. First report of binuclear oxovanadiumv complexes containing 4,4bipyridine type bridge. The pdf file you selected should load here if your web browser has a pdf reader plugin installed for example, a recent version of adobe acrobat reader if you would like more information about how to print, save, and work with pdfs, highwire press provides a helpful frequently asked questions about pdfs alternatively, you can download the pdf file.
Synthesis and characterization of some novel schiff base. The complexes are soluble in dmf and dmso but insoluble in organic solvents like methanol, ethanol and acetone. Oxovanadiumiv complexes of bioinorganic and medicinal. Download book pdf electron spin resonance of metal complexes pp 111 cite as. Vanadate and oxovanadium iv complexes are the key genus, survive in physiological situation. Download this pdf file the pdf file you selected should load here if your web browser has a pdf reader plugin installed for example, a recent version of adobe acrobat reader. The infrared spectra of the complexes in the range 4000200 cm1, were recorded in potassium bromide medium on perkinelmer 621 and beckmann acculab9 spectrophotometers. Synthesis and characterization of oxovanadiumiv complexes. The synthesised oxovanadiumiv complexes were characterized by elemental analysis, electrical conductance, magnetic moment measurements and spectral infrared, electronic and electron. The anionic complexes 3 and 6 catalyse the oxidative bromination of.
This article is from chemistry central journal, volume 7. The infrared spectra of all complexes have been recorded and are discussed in detail. Ferroelectric and mesomorphic properties of oxovanadiumiv. The prepared macrocyclic complexes were characterized by elemental analyses, molar conductance. Oxidation of benzoin catalyzed by oxovanadium iv schiff base complexes chemistry central journal, dec 20 tahseen a alsalim, jabbar s hadi, omar n ali, hanna s abbo, salam jj titinchi. The photocytotoxicity is found to correlate well with the hydrophobicity, photosensitizing ability and dna binding strength of the complexes. Oxovanadium iv complexes of curcumin for cellular imaging and mitochondria targeted photocytotoxicity article pdf available in dalton transactions 4335 july 2014 with 1,204 reads. The results indicate the enhanced activity of metal complexes over their parent ligands. Spermicidal activity of oxovanadiumiv complexes of 1,10. First report of binuclear oxovanadiumv complexes containing 4,4bipyridine.
The third vanadium binds to phenolic and keto oxygen atoms on rings b and c to form complex 1. Nov 06, 20 vanadium has ability to coordinate with multidentate ligands in different geometries to produce variety of complexes. Satisfactory data from the studies presented above correspond to the formulation of the complexes as vol 2 h 2 o. In an effort to study the spectral, magnetic, and stereochemical properties of vanadyl complexes, both a new series of vanadyl complexes derived from type vii ligands with subnormal. All structured data from the file and property namespaces is available under the creative commons cc0 license. Moreover, they show chelating properties towards vanadyl cation that could be used in insulinmimetic compound development. The complex of 5chlorooxine is very unstable and oxidizes rapidly, generating a vv complex of stoichiometry voqcl2oh which could also be prepared in pure form. Synthesis, characterization and bioactivities of some novel. Precipitation of 3 equiv of hnet3cl seemed to point to the clean formation of c. Characterization of new oxovanadiumiv complexes of saccharides. Oxovanadiumiv complexes of curcumin for cellular imaging and mitochondria targeted photocytotoxicity article pdf available in dalton transactions 4335 july 2014 with 1,204 reads. The onntype oxovanadiumv complexes showed higher catalytic activities than those of onnotype oxovanadiumv complexes, irrespective of the structure of the dienes. Nonoxovanadiumiv and oxovanadiumv complexes with mixed. Spectral studies of low symmetry oxovanadiumiv complexes.
Oxovanadiumiv and oxovanadiumv complexes relevant to biological systems cheminform abstract. An application of oxovanadium iv compounds as oxidation catalysts was first discovered by sharpless in the case of the regioselective epoxidation of allylic alcohols. If you would like more information about how to print, save, and work with pdfs, highwire press provides a helpful frequently asked questions about pdfs. The photocytotoxicity of complex 3 has been studied using. Hydroxypyrone derivatives have a good bioavailability in rats and mice and have been used in drug development. Photocytotoxic oxovanadiumiv complexes showing light. These complexes slowly transform into 9 and 10 in methanol, as confirmed by 1h, c and 51v nmr. Oxovanadium iv and oxovanadium v complexes relevant to biological systems baran, enrique j. Oxovanadiumiv complexes containing 1,10phenanthroline, 2,2. The complexes 1, 2, and 4 were more effective than metronidazole, a commonly used drug against amoebiasis, suggesting that oxovanadiumv complexes derived from thiohydrazones. Oxidation of benzoin catalyzed by oxovanadium iv schiff base complexes chemistry central journal, dec 20 tahseen a alsalim, jabbar s hadi, omar n ali, hanna s abbo, salam jj.
Pdf oxovanadiumiv complexes of curcumin for cellular. Oxovanadiumiv complexes of the monosaccharides d and larabinose, dgalactose, dmannose, dlyxose, dxylose and the disaccharide maltose were obtained in. Characterization of new oxovanadiumiv complexes of. Predicted data is generated using the us environmental protection agencys episuite. Schiff base complexes of aluminiumiii pdf free download. Studies on oxovanadium iv oxalate hydrates pdf free. The factors which contribute to the activity of these complexes are discussed. Therapeutic application of zinc and vanadium complexes.
Pdf oxovanadiumiv complexes have been synthesized and characterized the general composition vola. The oxalato complexes, voc2o42h2o and voc2o44h2o, are described. Some oxovanadiumiv complexes of sassa and 5, 10, 15, and 20meso tetraphenylporphyrin h2tpp with unidentate and bidentate nitrogen. The limits of practical utilization of these reagents involves the use of stoichiometric amounts of corrosive acids or. Graphene oxide go supported transition metal complexes are apprised as sturdy and everlasting heterogeneous catalysts. Solution speciation and spectral studies on oxovanadiumiv complexes of pyridinecarboxylic acids pdf. Synthesis and spectral studies of some oxovanadiumiv and. Oxidation of benzoin catalyzed by oxovanadiumiv schiff. Synthesis, structure, and spectroscopic properties oxovanadiumiv complexes. Oxovanadium complexes in bio medical applications request pdf.
Oxidation of benzoin catalyzed by oxovanadium iv schiff. Pdf urease inhibition of oxovanadiumv complexes with. Synthesis and characterization of oxovanadiumiv macrocyclic. The dna binding and nuclease activity of the synthesized. The names of the 11 oxovanadium complexes synthesized and tested in this study are listed in table 1.
The crystal structures of compounds i and ii are determined using singlecrystal xray diffraction. Jan 29, 2010 in the context of a potential modeling of reduced oxovanadium species occurring on the surfaces of silicasupported vanadia catalysts in the course of its turnover, the incompletely condensed silsesquioxane h3cpentylt7 was reacted with cl4vthf2 where thf tetrahydrofuran in the presence of triethylamine. The chiral and racemic oxovanadium iv salmmen complexes, voxc16salmmen x r1, s2, and rac3. Oxovanadiumiv complexes with onnochelating ligands as. Oxovanadiumiv coordination compounds with kojic acid. Oxovanadiumiv complexes with onno chelating ligands as catalysts for ethylene homo and copolymerization by marzena bialek, anna leksza, anna piechota, krzysztof kurzak and katarzyna koprek download pdf. This page was last edited on 21 december 2007, at 20. Bisacetylacetonatooxovanadium c10h14o5v i and s2nsalicylideneaminopropionateoxovanadium monohydrate c10h9no5v ii are synthesized.
The interest in the chemistry of oxovanadium complexes has. Oxovanadiumiv complexes with onnotype tetradentate schiff base ligands. The colour of these complexes vary from green to snuff. Coordination of bf4 to oxovanadiumv complexes, evidenced. The thermal decomposition behaviours of oxovanadiumivhydroxamate complexes of composition voq 2. Synthesis and catalytic properties of manganeseii and. The complexes 79 analyzed for cl and s and the molar conductance was found. In the context of a potential modeling of reduced oxovanadium species occurring on the surfaces of silicasupported vanadia catalysts in the course of its turnover, the. The complexes 1, 2, and 4 were more effective than metronidazole, a commonly used drug against amoebiasis, suggesting that oxovanadium v complexes derived from thiohydrazones may open a new. If the inline pdf is not rendering correctly, you can download the pdf file. Vanadyl sulphate can easily exchange its sulphate group with organic ligands. Oxovanadiumiv and v complexes of dithiocarbazatebased. Download pdf abstractexcerpt full text pdf references.
Research article open access oxidation of benzoin catalyzed by oxovanadium iv schiff base complexes tahseen a alsalim1, jabbar s hadi1, omar n ali1, hanna s abbo2 and salam. Oxovanadiumiv complexes containing voons basic core. Their sodium salts were precipitated with absolute ethanol and characterized by uvvis spectroscopy absorption and reflectance, thermoanalytical tg and dta. A series of oxovanadiumiv complexes of the type vomacso 4 where mac tetraazamacrocyclic ligands derived from condensation of 4,4,4trifluro12furyl1,3butanedione or 4,4,4trifluro12thenyl1,3butanedione with pphenylenediamine and their reaction with. A study of the organic complexes of oxovanadium iv richard clement skevington wollongong university college unless otherwise indicated, the views expressed in this thesis are those of. Structural parameters of the oxovanadium assemblies are compiled, which reveal the preference of specific coordination geometries around vanadium atoms according to the. Oxovanadium complexes with multidentate ligands oxovanadium complexes with multidentate ligands munawar, khurram. Thermal studies of some biologically active oxovanadiumiv. The complexes are analyzed for carbon, hydrogen, nitrogen, sulphur.
Oxovanadium forms 5coordinate complexes in all the three complexes. The oxidative transformation of benzoin to benzil has been accomplished by the use of a wide variety of reagents or catalysts and different reaction procedures. Oxovanadium complexes with multidentate ligands request pdf. When garlic is stored for long periods of time, it can form visible. Spectral data and elemental analysis of all the synthesized ligands and their oxovanadium iv complexes were in good agreement with their structure, indicating the high purity of all the compounds. Moreover, they show chelating properties towards vanadyl cation that could be. Another new series of four oxovanadiumiv complexes involving o, n donor environment of. The oxovanadium complexes have a square pyramidal geometry with the oxo ligand o 2.
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